{"id":11776,"date":"2025-11-05T11:18:56","date_gmt":"2025-11-05T10:18:56","guid":{"rendered":"https:\/\/fermi.univ-tlse3.fr\/?post_type=tribe_events&#038;p=11776"},"modified":"2025-11-13T11:22:41","modified_gmt":"2025-11-13T10:22:41","slug":"evolution-of-chemical-and-physical-transformations-under-electron-beams-light-and-mechanical-impact-dominik-lungerich-cemes-seminar-21-11-2025-11-h","status":"publish","type":"tribe_events","link":"https:\/\/fermi.univ-tlse3.fr\/fr\/home\/event\/evolution-of-chemical-and-physical-transformations-under-electron-beams-light-and-mechanical-impact-dominik-lungerich-cemes-seminar-21-11-2025-11-h\/","title":{"rendered":"Evolution of chemical and physical transformations under electron beams, light, and mechanical impact. &#8211; (Dominik Lungerich \/ CEMES \/ Seminar). &#8211; 21\/11\/2025, 11 H"},"content":{"rendered":"<p><span style=\"font-size: 20px; background-color: #f18500;\">S\u00e9minaire du CEMES<\/span><\/p>\n<p><span style=\"font-size: 20px;\"><span style=\"color: #191970;\"><strong>Dominik Lungerich, <\/strong><\/span>CEMES <\/span><\/p>\n<p><span style=\"background-color: #cecece;\">Seminar CEMES, 21\/11\/2025, 11H<\/span><\/p>\n<p style=\"text-align: justify;\"><strong>Summary<\/strong><br \/>\nThe advent of aberration-corrected transmission electron microscopy (AC-TEM) has revolutionized materials science and adjacent disciplines, enabling researchers to capture atomic-level details with unprecedented precision. Among these developments, single-molecule atomic-resolution time-resolved electron microscopy (SMART-EM) has emerged as a powerful approach to visualize dynamic events at the molecular and atomic scale in real time.<\/p>\n<p style=\"text-align: justify;\">My research integrates these microscopic insights with chemical understanding\u2014through the lens of an organic chemist\u2014to elucidate reaction mechanisms driven by electron beams.<strong>[1\u20135]<\/strong> Using high-resolution imaging, complemented by image simulations and density functional theory calculations, we demonstrate the controlled formation of carbon nanostructures at the molecular level. These results establish electron-beam chemistry as a distinct and complementary approach to conventional thermal, photochemical, and mechanochemical methods.<\/p>\n<p style=\"text-align: justify;\">Using light as an energy source, I investigate molecular photoswitches as building blocks for responsive and mechanically active materials.<strong>[6]<\/strong> Among them, azobenzenes\u2014undergoing a pronounced geometrical change from ~1 nm (trans) to ~0.5 nm (cis)\u2014represent some of the most promising actuators. Inspired by biological muscle systems, we tailor their response through dopants and environmental modulation, creating complex multiresponsive materials that can be triggered by stimuli beyond light alone.<\/p>\n<p style=\"text-align: justify;\">Finally, mechanochemically assisted synthesis continues to gain importance in both academia and industry but remains limited by an incomplete understanding of reaction kinetics. In particular, dependencies on the type and dynamics of milling equipment are poorly understood and often overlooked. To address this, I identify critical kinetic parameters using kinematic models, enabling reproducibility and cross-comparison of mechanochemical reactions across commonly used planetary and mixer mills.<strong>[7]<\/strong><\/p>\n<p style=\"text-align: justify;\">Together, these studies illustrate how directed energy inputs\u2014electronic, photonic, and mechanical\u2014can drive and control chemical transformations with spatial and temporal precision, expanding the boundaries of molecular design and materials engineering.<\/p>\n<p><strong>References<\/strong>:<\/p>\n<ul>\n<li><strong>[1]<\/strong> J.-Y. Yoon, D. Lungerich* et al., \u201cUnderstanding Electron Beam-Induced Chemical Polymerization Processes of Small Organic Molecules Using Operando Liquid-Phase Transmission Electron Microscopy\u201d ACS Nano 2025, 19, 10889\u201310901.<\/li>\n<li><strong>[2]<\/strong> M. Lin, D. Lungerich*, J. Cheon* et al., \u201cA magnetically powered nanomachine with a DNA clutch\u201d Nat. Nanotechnol. 2024, 19, 646\u2013651.<\/li>\n<li><strong>[3]<\/strong> J. Park, D. Lungerich*, \u201cElectron beam-induced demetallation of Fe, Co, Ni, Cu, Zn, Pd, and Pt metalloporphyrins: insights in e-beam chemistry and metal cluster formations\u201d Phys. Chem. Chem. Phys. 2024, 26, 8051\u20138061.<\/li>\n<li><strong>[4] <\/strong>H. Hoelzel, D. Lungerich* et al., \u201cTime-resolved imaging and analysis of the electron beam-induced formation of an open-cage metallo-azafullerene\u201d Nat. Chem. 2023, 15, 1444\u20131451.<\/li>\n<li><strong>[5]<\/strong> T. Shimizu, D. Lungerich*, K. Harano*, E. Nakamura*, \u201cTime-Resolved Imaging of Stochastic Cascade Reactions over a Submillisecond to Second Time Range at the Angstrom Level\u201d J. Am. Chem. Soc. 2022, 144, 9797\u20139805.<\/li>\n<li><strong>[6]<\/strong> A. Ayadi, D. Lungerich* et al., \u201cSynthesis and Photophysical Analysis of Amphiphilic Azobenzene Surfactants for Photomechanical Actuation\u201d Eur. J. Org. Chem. 2025, 28, e202500250.<\/li>\n<li><strong>[7] <\/strong>O. F. Jafter, D. Lungerich* et al., \u201cNavigating Ball Mill Specifications for Theory\u2010to\u2010Practice Reproducibility in Mechanochemistry\u201d Angew. Chem. Int. Ed. 2024, e202409731<\/li>\n<\/ul>\n<hr \/>\n<p><div class=\"leaflet-map WPLeafletMap\" style=\"height:300px; width:70%;\"><\/div><script>\nwindow.WPLeafletMapPlugin = window.WPLeafletMapPlugin || [];\nwindow.WPLeafletMapPlugin.push(function WPLeafletMapShortcode() {\/*<script>*\/\nvar baseUrl = atob('aHR0cHM6Ly97c30udGlsZS5vcGVuc3RyZWV0bWFwLm9yZy97en0ve3h9L3t5fS5wbmc=');\nvar base = (!baseUrl && window.MQ) ?\n    window.MQ.mapLayer() : L.tileLayer(baseUrl,\n        L.Util.extend({}, {\n            detectRetina: 0,\n        },\n        {\"subdomains\":\"abc\",\"noWrap\":false,\"maxZoom\":18}        )\n    );\n    var options = L.Util.extend({}, {\n        layers: [base],\n        attributionControl: false\n    },\n    {\"zoomControl\":true,\"scrollWheelZoom\":true,\"doubleClickZoom\":true,\"fitBounds\":true,\"minZoom\":9,\"maxZoom\":18,\"maxBounds\":null,\"attribution\":\"<a href=\\\"http:\\\/\\\/leafletjs.com\\\" title=\\\"Une biblioth\\u00e8que JS pour des cartes interactives\\\">Leaflet<\\\/a>; \\u00a9 <a href=\\\"http:\\\/\\\/www.openstreetmap.org\\\/copyright\\\">OpenStreetMap<\\\/a> contributeurs\"},\n    {});\nwindow.WPLeafletMapPlugin.createMap(options).setView([43.579318389757,1.462611999468],16);window.WPLeafletMapPlugin.createScale({});});<\/script><br \/>\n<script>\nwindow.WPLeafletMapPlugin = window.WPLeafletMapPlugin || [];\nwindow.WPLeafletMapPlugin.push(function WPLeafletMarkerShortcode() {\/*<script>*\/\nvar map = window.WPLeafletMapPlugin.getCurrentMap();\nvar group = window.WPLeafletMapPlugin.getCurrentGroup();\nvar marker_options = window.WPLeafletMapPlugin.getIconOptions({});\nvar marker = L.marker(\n    [0,0],\n    marker_options\n);\nvar is_image = map.is_image_map;\n    marker.setLatLng( map.getCenter() );\nif (marker_options.draggable) {\n    marker.on('dragend', function () {\n        var latlng = this.getLatLng();\n        var lat = latlng.lat;\n        var lng = latlng.lng;\n        if (is_image) {\n            console.log('leaflet-marker y=' + lat + ' x=' + lng);\n        } else {\n            console.log('leaflet-marker lat=' + lat + ' lng=' + lng);\n        }\n    });\n}\nmarker.addTo( group );\nmarker.bindPopup(window.WPLeafletMapPlugin.unescape('CEMES'));window.WPLeafletMapPlugin.markers.push( marker );\n        });<\/script><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Lieu : salle de conf\u00e9rence du CEMES<\/p>\n","protected":false},"author":5,"featured_media":0,"template":"","meta":{"neve_meta_sidebar":"","neve_meta_container":"","neve_meta_enable_content_width":"","neve_meta_content_width":0,"neve_meta_title_alignment":"","neve_meta_author_avatar":"","neve_post_elements_order":"","neve_meta_disable_header":"","neve_meta_disable_footer":"","neve_meta_disable_title":"","neve_meta_reading_time":"","_tribe_events_status":"","_tribe_events_status_reason":"","footnotes":""},"tags":[],"tribe_events_cat":[306,48,233],"class_list":["post-11776","tribe_events","type-tribe_events","status-publish","hentry","tribe_events_cat-cemes","tribe_events_cat-events","tribe_events_cat-seminars","cat_cemes","cat_events","cat_seminars"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.5 - 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